You can change the email address from which you send emails in the Outlook desktop app.
To change your default email account:
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From Outlook, select File on the top-left corner.
- Select Account Settings, then select Account Settings again.
- From the list of accounts on the Email tab, click on the account you want to use as the default account.
- Select Set as Default.
- Select Close.
Next, set your default email account as sending email address:
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Select File on the top-left corner.
- Select Options from the bottom-left corner. The Outlook Options window will open.
- Click on Mail from the left panel and scroll down to the Send Messages section.
- Tick the box next to Always use the default account when composing new messages.
- Select OK to save.